Ethylene oxide monitor with part-per-trillion precision for in situ measurements
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Published:2023-04-13
Issue:7
Volume:16
Page:1915-1921
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ISSN:1867-8548
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Container-title:Atmospheric Measurement Techniques
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language:en
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Short-container-title:Atmos. Meas. Tech.
Author:
Yacovitch Tara I.ORCID, Dyroff Christoph, Roscioli Joseph R., Daube ConnerORCID, McManus J. Barry, Herndon Scott C.ORCID
Abstract
Abstract. An Aerodyne tunable infrared laser direct absorption spectrometer with a multipass cell with a 413 m pathlength for the detection of ethylene oxide (EtO) is presented (TILDAS-FD-EtO). This monitor achieves precisions of <75 ppt or <0.075 ppb s−1 and <20 ppt in 100 s (1σ). We demonstrate precisions averaging down to 4 ppt h−1 (1σ precision) when operated with frequent humidity-matched zeroes. A months-long record of 2022 ambient concentrations at a site in the eastern United States is presented. Average ambient EtO concentration is on the order of 18 ppt (22 ppt standard deviation, SD). Enhancement events of EtO lasting a few hours are observed, with peaks as high as 600 ppt. Back-trajectory simulations suggest an EtO source nearly 35 km away. This source along with another are confirmed as emitters through mobile near-source measurements, with downwind concentrations in the 0.5 to 700 ppb range depending on source identity and distance downwind.
Funder
U.S. Environmental Protection Agency
Publisher
Copernicus GmbH
Subject
Atmospheric Science
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