Dielectric Investigations and Theoretical Calculations of Size Effect in Lead Titanate Nanocrystals

Author:

Grigalaitis Robertas1,Banys Juras1,Lapinskas Saulius1,Erdem Emre2,Boettcher Rolf2,Glaesel H. Juergen3,Hartmann Eberhard4

Affiliation:

1. Vilnius University

2. Universität Leipzig

3. Leibniz Institute of Suface Modification (IOM e.V.)

4. Leibniz Institute of Surface Modification (IOM e.V)

Abstract

In this paper the dielectric properties of nanosize ferroelectric lead titanate crystals are presented. The PbTiO3 samples were prepared by pressing nanopowder into the plates and have been studied experimentally by dielectric permittivity measurements in a wide frequency and temperature range. The obtained TC dependence shows a critical change of behavior with increasing of mean nanoparticle size in a 9 nm region. The theoretical calculations based on Monte Carlo simulation were performed to describe such behavior of this material. It was shown that taking into account distribution of nanoparticle sizes in sample is possible to describe dielectric properties of PbTiO3 nanocrystals rather well.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Reference11 articles.

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3. G. Arlt, D. Hennings and G. de With: J. Appl. Phys. Vol 58, (1985), p.1619.

4. D.A. Payne and L.E. Cross: in Microstructure and Properties of Ceramic Materials, edited by T. S Yen and J. A Pask (Science Press, Bejing 1984).

5. A. Yu. Emelyanov, N. A Pertsev, S. Hoffmann-Eifert, U. Böttger and R. Waser: Journal of Electroceramics Vol. 9, (2002), p.5.

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1. Correlation between Microstructure and Electrical Properties of Ferroelectric Relaxors;Nanoscale Ferroelectrics and Multiferroics;2016-03-25

2. Size effects in a relaxor: further insights into PMN;Journal of Physics: Condensed Matter;2014-06-13

3. Study of the tetragonal-to-cubic phase transition in PbTiO3nanopowders;Journal of Physics: Condensed Matter;2006-03-30

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