Study on Synthesis and Properties of Waterborne Polyurethane Modified by Epoxy Resin

Author:

Jin Zhi Ming1,Guo Wen Lu1,Gao Cai Hua1

Affiliation:

1. Jiangsu University of Science and Technology

Abstract

The waterborne polyurethane (WPU) modified by epoxy resin was synthesized by using isophorone diisocyanate (IPDI), poly propylene glycol (PPG-1000), 2,2-dimethylol propionic acid (DMPA) and epoxy resin as the main raw materials. The WPU properties were characterized by TGA, FTIR, and so on. The study shows that whennNCO/nOH=1.4, the mount of DMPA is 5.0%, the emulsifying property of WPU which is modified epoxy resin with high epoxy value is well. And when the mounts of E-20, E-44 are 2.0%, 4.0% respectively, the synthesized emulsion with small size has well stability. The modified WPU which possesses high hardness, low water absorption, good heat resistance and anticorrosion, has a well combination property.

Publisher

Trans Tech Publications, Ltd.

Reference5 articles.

1. Jui-Ming Yeh, Chia-Tseng Yao, Chi-Fa, et al. European Polymer Journal. Vol. 44(2008), pp.3046-3056.

2. Hsun-Tsing Lee, Sheng-Yen Wu, Ru-Jong Jeng. Colloids and Surfaces A. Vol. 276(2006), pp.176-185.

3. Guowen Hu. FINE CHEMICALS. Vol. 28(2011), P. 1-6 (in Chinese).

4. Likun Li. POLYURETHANE INDUSTRY. Vol. 25(2010), pp.42-45 (in Chinese).

5. Xiang YI, De-liang HE, Zhen-jun WU, Li-ping HE. Modern Paint & Finishing. Vol. 12(2009), pp.13-15 (in Chinese).

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