Development of Glass Ceramic by Sintering and Crystallization of Glass from Phosphorus Slag

Author:

Lin Qian1,Cao Jian Xin1,Fu Cheng Bing2,Zhang Yuan3

Affiliation:

1. South China University of Technology

2. Guizhou University

3. Chinese Research Academy of Environmental Sciences

Abstract

The phosphorus slag produced as the waste of yellow phosphorus manufacturing was studied for the production of calcium-aluminum-silicone system glass ceramic materials. The thermal behavior and crystallization processes of fine powders of parent glass with chemical composition (wt. %) 52-60 SiO2, 22-28 CaO, 2-10 Al2O3, 3-8Na2O+K2O, 1.7-2.1P2O5 and 1.6-2.0 F were carefully studied by DTA, XRD and SEM techniques. The desired sequence of events, i.e. nucleation, sintering and devitrification occurred by heat treating the glass powder. The results showed that the phosphorus slag can be as a main raw material directly in production of the glass ceramic.

Publisher

Trans Tech Publications, Ltd.

Subject

Mechanical Engineering,Mechanics of Materials,General Materials Science

Reference3 articles.

1. J.X. Cao, Q. Lin, Q.L. Chen, et al.: Modern Machinery Vol. 108 (2001), p.78.

2. J.X. Cao, C.B. Fu, Y. Zhang, et al.: J. Guizhou Univ. Technol. Vol. 32 (2003), p.33.

3. D.U. Tulyaganov, M.J. Ribeiro and J.A. Labrincha: Ceram. Inter. Vol. 28 (2002), p.515. Fig. 5 SEM observation of the glass- ceramic sample heat-treated at 920°C.

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