Adsorption Behavior and Corrosion Inhibition of EPP for Q235 Steel in H2SO4 Solution

Author:

Zou Li Ke1,Lai Chuan1,Xie Bin1,Yang Xue2,Xiang Zhen3,Zeng Ni3,Huang Chun3,Wang Yang Mei3

Affiliation:

1. Sichuan University of Science & Engineering

2. Chengdu University of Technology

3. Sichuan University of Science and Engineering

Abstract

The inhibition effect of N,N-diethylammonium O,O'-di(2-phenylethyl)dithiophosphate (EPP, [NH2(Et)2][S2P(OCH2CH2Ph)2]2) against the corrosion of Q235 steel in H2SO4solution was studied by weight loss measurement, potentiodynamic polarization and SEM(scanning electron microscope) techniques. The results show that EPP acts as an excellent corrosion inhibitor in 5% H2SO4by suppressing simultaneously the cathodic and anodic processes via chemical adsorption on Q235 steel surface, which complies with the Langmuir adsorption isotherm. Polarization curves indicate EPP is a mixed-type inhibitor. The effects of temperature, acid concentration and immersion time were also studied.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

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