Effect of Single Walled Carbon Nanotubes on the Series Resistance and Trap Energy of Malachite Green Dye Based Organic Device

Abstract

In this paper, we have estimated the series resistance (Rs) and the trap energy (Ec) of the sandwiched type Malachite Green (MG) dye-based organic device and have also observed the influence of single-walled carbon nanotubes (SWCNT) on both of these parameters. To form the organic device, we have used Indium Tin Oxide (ITO) coated glass as the front electrode and Aluminium (Al) as a back electrode by using the spin coating technique. The values of series resistance are measured from both I-V characteristics and by utilizing Cheung Function due to the non ideal behavior of organic devices. We have also extracted the values of Rs by using H (I) versus I plot and verified the values with the measured values of Rs from the Cheung function. The extracted values of series resistance using these three processes remain consistent with each other in showing that the values of series resistance have been reduced considerably in the presence of SWCNT. The trap energy has been estimated from the steady-state current-voltage characteristics. There is a significant correlation in between series resistance and the trap energy of the organic device. The presence of Single-Walled Carbon Nanotubes reduces the trap energy from 0.086 eV to 0.057 eV. Lowering of the trap energy of the metal-organic layer interface in presence of Single Walled Carbon Nanotubes attributes to the reduction of the value of the series resistance. The extracted value of Rs decreases from 0.154 MΩ to 0.0389 MΩ in presence of SWCNT. Decrease in the value of both of these parameters in the presence of SWCNT will definitely improve the charge transport mechanism of the organic device and thereby the conductivity.