Synthesis, Characterization and Fluorescent Properties of Complex Fluoride BaNiF4: Ce3+

Author:

Tian Hai Yan1,Shen Hai Yun1,Yang Qiu Hua1,Wang Xue Juan1

Affiliation:

1. Tianjin University

Abstract

The complex fluoride BaNiF4:Ce3+ was synthesized by reflux method using ethylene glycol as reaction solvent at its boiling point temperature. The sample was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and fluorescence spectrophotometer. The results indicated that the mean particle diameter of BaNiF4:Ce3+ was 53.8 nm. Only adsorption oxygen (α oxygen) existed on the surface of BaNiF4: Ce3+ and the content of surface oxygen was ≤5%. The maximum emission peak of BaNiF4:Ce3+ was 350 nm in its luminescent spectrum, and emission band of Ce3+ belonged to 5d→4f transition.

Publisher

Trans Tech Publications, Ltd.

Subject

General Engineering

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