Occurrence and identification of microplastics retained in corrosion deposits of drinking water transmission pipes

Abstract

The irregular structure and high porosity of corrosion deposits create suitable conditions for the retention, accumulation and adsorption of microplastics (MPs) and nanoplastics (NPs) transported by distributed water. Due to the low mass and continuous degradation of MPs, under certain conditions (e.g., changes in water composition or hydraulic conditions, network failures), these particles can be re-released into the water, causing secondary contamination. This paper presents preliminary results on the degree of MP contamination of sediments lining the inner surface of metal alloy pipes taken from a municipal drinking water distribution network. The isolated particles were assessed in terms of number, shape, residence time in the network, and origin. Plastic fragments classified as MPs and NPs were found in all analyzed corrosion deposits. Fragments smaller than 50 μm predominated, indicating a high level of plastic fragmentation associated with advanced degradation and prolonged residence in the environment. The predominant plastics identified were polyethylene (PE), polyethylene terephthalate (PET), and polyamides. High-carbon particles, most likely NP particles, whose presence in drinking water may pose a high health risk to consumers due to their potential to migrate into body tissues, were very abundant in the sediments but impossible to count with the techniques used. The results indicate the need to intensify research on the content of MPs and NPs not only in drinking water, but also in the sediments covering the interior of distribution pipes, and to identify factors that may cause their secondary release into bulk water.