Affiliation:
1. Department of Chemistry, Vivekanandha College of Arts and Sciences for Women (A), Elayampalayam, Tiruchengode-637205, India
2. Department of Chemistry, Thiruvalluvar Government Arts College, Rasipuram-637401, India
Abstract
In this study, the durability of polyurethane adhesives are successfully developed using
silane-functionalized polybenzoxazine@CeO2 nanocomposites. The electrochemical measurements
were used to investigate the mechanical strength of polybenzoxazine nanocomposite with polyurethane
materials. The superior results in the process of passivation film that also controlled the dissolution of
metal have been characterized by UV-visible, XRD, SEM/EDX, FT IR, TGA-DTA-DSC, micro
hardness, gel absorption and water absorption analyses. The mechanical performance of the coated
surface that supported up the electrochemical investigations was enhanced by the incorporation of
silane functionalized polybenzoxazine@CeO2 nanocomposites with polyurethane. The use of
ployurthane in the TGA process increases the cross-linked density of the coating, resulting in high
thermal stability. As a result of their superior anticorrosive property, the proposed
polybenzoxazine@CeO2 nanocomposites with polyurethane films offer the openings for the
development of unique, state-of-the-art anticorrosive adhesives across a wide range of sectors.
Publisher
Asian Journal of Chemistry