Affiliation:
1. Department of Physics, Koneru Lakshmaiah Education, Vaddeswaram-522502, India
Abstract
In this experimental investigation, the thermodynamic fundamental parameters of density (ρ) and
speed of sound(U) were calibrated for aqueous solution/alcoholic (1-propanol and 2-propanol) solutions
of piperidinium based ionic liquids of 1-butyl-1-methylpiperidinium tetrafluoroborate (BMPiBF4) in
various concentrations within temperatures from 303.15 to 313.15 K. From these experimental
determined values, various thermodynamic acoustic parameters of excess molar isentropic
compressibility (KE
s,m), excess molar volume (VE
m) are expressed in specific and non-specific molecular
interactions. Moreover, calibration of the partial molar volume′s and partial isentropic compressibility′s
of both components shows strong interaction in BMPiBF4 + 2-proponol combination than any other
executed binary composites. In addition to this, the FTIR characteristic spectrum of all combinations
at different concentrations gives the more promising features such as interaction behaviour that helps
our analysis to guide the interactions of individual bonds.
Publisher
Asian Journal of Chemistry