MORPHOLOGICAL EVOLUTION OF Al2O3 AND CNT NANOFLUID DROPLETS DURING SOLIDIFICATION

Abstract

Nanofluid is an emerging heat transfer fluid with good heat transfer and thermal conductivity properties. It is important to investigate the phase change properties and morphological evolution during the freezing of nanofluid droplets to understand their practical applications. The effect of dynamic wettability on the deformation of a single droplet of aluminum trioxide (Al₂O₃-H₂O) and graphene (CNT-H₂O) nanofluids at different mass concentrations and substrate temperatures was investigated by visualizing the droplet freezing. The formation of solid-like and freezing front motions inside the droplet during the freezing process of these droplets was investigated. The solidification process was strongly influenced by the temperature gradient perpendicular to the cold surface and the change in the solid–liquid interface wettability during the phase change, resulting in volume redistribution at the top of the droplet. The freezing shape of Al₂O₃-H₂O nanodroplets resembled a "moon crater," and the influence of wettability decreased with increasing concentration, leading to a relative increase in the aperture of the top platform. The fully frozen state of the nanofluid droplet had an increasingly pointed tip, with a strong relationship between the substrate temperature and solidification time when the CNT-H₂O concentration was 5 times higher and showed no change in the freezing droplet deformation rate under the experimental conditions. The contact angle of the two nanofluid droplets did not fluctuate significantly with increasing concentration, while that of the 1% nanofluid droplets remained at an average value of 85° during freezing. Under different freezing conditions, the freezing shape of Al₂O₃-H₂O droplets tended to increase in diameter as the subcooling temperature decreased, with the final deformation rate of 1% Al₂O₃-H₂O being twice that at 5% concentration, while the contact angle of the same mass concentration of Al₂O₃-H₂O decreased by 1° as the subcooling temperature dropped. The CNT-H₂O droplet became sharper at the tip as the subcooling temperature increased, and its contact angle did not change with temperature.