Compound Development of Fe₈₀Cr₂₀ Metallic Interconnect by Ball Milling and Ultrasonic Technique: Its Effect on Mass Gradation

Abstract

The investigation of metallic material for interconnect fuel cell application was very challenging due to interconnect operate at high temperature up to 1100⁰C. However, the main problem of metallic material is mass change at high temperature is inevitable. Therefore, this research aims to analyse the compound of Fe₈₀Cr₂₀ and it effect of mass gradation. The methods were conducted by ultrasonic technique (UT) by frequency of 35 kHz, various ultrasonic time of 3, 3.5, 4, 4.5 and 5 h. Milling technique was conducted by milling time of 60 h with nitrogen gas condition. The analysis was conducted by Scanning Electron Microscope for compound investigation and Thermo Gravimetric Analyzer (TGA) for mass gradation analysis. The result shows that there are several compounds that developed after ball milling and ultrasonic technique such as Fe₈₀Cr₂₀, FeO₂ and Cr₂O₃. The UT samples shows the lowest mass gain of 31.917 mg is located at UT 4.5 h, while raw material has largest mass gain as compared to the other samples (treated samples). Meanwhile for milled and combination of milled and UT samples shows the lowest mass gain has observed at milled and UT 4.5 h with the value of 17.014 mg and 12.7 mg, respectively.