Self Absorption Corrections for X-Ray Fluorescence Analysis of Aerosols

Author:

Dzubay T. G.,Nelson R. O.

Abstract

AbstractA procedure is described for making self absorption corrections for x-ray fluorescence analysis of ambient air aerosols which are collected in two size ranges with a dichotomous sampler. Calculations for fine particles are based on the assumption of a uniform layer of accumulated deposit which has an exponentially decreasing depth profile within a membrane filter. Coarse particles are treated as spheres with a log normal mass distribution which is subject to modification by the sampling device. An average attenuation and the associated uncertainty is deduced for coarse particles by considering a wide variety of possible chemical compositions.

Publisher

Cambridge University Press (CUP)

Reference13 articles.

1. Goulding F. S. and Jaklevic J. M. , “X-Ray Fluorescence Spectrometer for Airborne Particulate Monitoring”, EPA Report No. EPA-R2-73-182 (1973).

2. Loo B. W. and Jaklevic J. M. , “An Evaluation of the ERC Virtual Impactor”, Lawrence Berkeley Laboratory Publication, LBL-2468, Berkeley (1974).

3. Physical mechanisms governing the dynamics of Los Angeles smog aerosol

4. Lundgren D. A. , “Mass Distribution of Large Atmospheric Particles”, Ph.D. Thesis, University of Minnesota (1973).

5. The aerosol size distribution of Los Angeles smog

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