Molecular Rearrangement of Longifolene by Arthrobacter ilicis T 2

Author:

Bhosle S.1,Kaliwal S. M.1,Paknikar S. K.1,Mavinkurve S.1

Affiliation:

1. Department of Microbiology and Department of Chemistry, 2 Goa University, Taleigao Plateau, Goa 403 203, India

Abstract

Arthrobacter ilicis T 2 brings about a unique type of cometabolic structural rearrangement of longifolene, a sesquiterpene, resulting in the formation of an acid. Infrared, nuclear magnetic resonance, mass spectrometry, and decoupling studies indicate that the acid product has a sativenelike structure, which is confirmed by conversion of the acid to its methyl ester and hydrocarbon.

Publisher

American Society for Microbiology

Subject

Ecology,Applied Microbiology and Biotechnology,Food Science,Biotechnology

Reference21 articles.

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3. Organoalkoxysilanes, Organosilanols, and Organosiloxanols;The Handbook of Environmental Chemistry;1997

4. Biodegradation of dimethylsilanediol in soils;Applied and Environmental Microbiology;1996-12

5. Natural sesquiterpenoids;Natural Product Reports;1995

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