Author:
N.F. Sadiyeva, Y.P. Cherepnova, S.A. Iskenderova N.F. Sadiyeva, Y.P. Cherepnova, S.A. Iskenderova,L.M. Afandiyeva, E.M. Guliyeva L.M. Afandiyeva, E.M. Guliyeva
Abstract
The article presents a one-stage method for the synthesis of effective plasticizers and antioxidants with a heterogeneous catalyst under mild conditions with a high yield. In order to obtain plasticizers and antioxidants, a number of studies were carried out to determine the optimal temperature, amount of catalyst and molar ratio of reacting components based on natural petroleum and aliphatic fatty acids (C6-C8) using a heterogeneous catalyst. Based on the studies carried out under optimal conditions (temperature -110-120°C, the amount of catalyst – 1,5 wt.%, acid, the molar ratio of components - acid: alcohol - 2:1,4), mixed diesters were synthesized with a yield of 88-90%. To confirm the structures of the synthesized diesters on the "Alpha" IR Fourier spectrometer, the corresponding IR-spectra were obtained, where the absorption bands characteristic of the carbonyl and ester functional groups appear with greater intensity. The good compatibility of the synthesized plasticizers with the polymer matrix and the effect of these compounds on the reduction of sludge in diesel fuel are shown.
Keywords: 1,4-butanediol, natural petroleum acids, mixed diesters, diesel fuel, polyvinyl chloride, plasticizer, antioxidant.
Publisher
Azerbaijan State Oil and Industry University
Reference15 articles.
1. Hilal M., Fam S.A., El-Sukkary M.M. et al. Naphthenate esters as PVC plasticizers – synthesis and evaluation of some esters. Erdol Kohle Erdgas Petrochemie.1995, Vol.48, №1, pp.24
2. Sadiyeva N., Iskandarova S., Cherepnova Y., Afandiyeva L., Nasibova G. Esters of aliphatic dibasic acids – promising plasticizers. Baku State University,“Modern problems of theoretical and experimental chemistry” devoted to the 90th anniversary of academician Rafiga Aliyeva, Baku. 29-30.09.2022, pp. 212-213
3. Sadiyeva N.F., İskenderova S.A., Cherepnova Y.P., Afandiyeva L.M., Nasibova G.G., İskenderova V.R. "Synthesis of a new antioxidant based on natural petroleum acids". Republican scientific conference dedicated to the 110th anniversary of Ali Musa oglu Guliyev: "Organic substances and composition materials of various purposes", Baku. 30-31.05.2022, pp. 44-45
4. Sadiyeva N., Isgandarova S., Afandiyeva L., Cherepnova Yu., Bagirova M., Asadova Sh. The synthesis of mixed diester of natural petroleum acids 10th Rostocker International Conference: “Technical Thermodynamics: Thermophysical Properties and Energy Systems”, Germany. 09-10.09.2021, pp.133
5. Zeynalov E.B., Maheramova Sh.N., Sadiyeva N.F., Iskenderova S.A. New softeners for polyvinylchloride. Materials Testing, Germany. 2012, Vol.54, №4, pp.246-248. https://doi.org/10.1515/mt-2020-620602