Impact of deposition temperature on electrical properties of HZO-based FeRAM

Author:

Yeh Yu-Hsuan1ORCID,Tan Yung-Fang2ORCID,Huang Yen-Che2,Lin Chao Cheng3,Wu Chung-Wei1,Zhang Yong-Ci2,Lee Ya-Huan1,Chang Ting-Chang4ORCID,Sze Simon M.5

Affiliation:

1. Department of Physics, National Sun Yat-sen University 1 , Kaohsiung 804, Taiwan

2. Department of Materials and Optoelectronic Science, National Sun Yat-sen University 2 , Kaohsiung 804, Taiwan

3. Taiwan Semiconductor Research Institute 3 , No. 26, Prosperity Road 1, Hsinchu 300, Taiwan

4. Department of Physics, College of Semiconductor and Advanced Technology Research, and also with the Center of Crystal Research, National Sun Yat-Sen University 4 , Kaohsiung 804, Taiwan

5. Department of Electronics Engineering and Institute of Electronics, National Yang Ming Chiao Tung University 5 , Hsinchu 300, Taiwan

Abstract

This study presents a comprehensive investigation of the impact of the deposition temperature on the HfxZr1−xO2 (HZO) ferroelectric layer of ferroelectric random access memory with TaN electrodes. This investigation mainly focuses on its electrical characteristics and compares the differences. It is revealed that the deposition temperature plays a crucial role in determining the crystal structure of HZO, which can exhibit a combination of tetragonal and orthorhombic phases or exist solely in one of the two phases. Furthermore, the grain size of HZO varies with the deposition temperature. These findings correspond well to the electrical measurement results, including leakage current, polarization, capacitance, and reliability tests. The study tracks the phase transition process during the operation of switching cycles when the phase transition process can be monitored as well. To better understand the observed differences, physical models that shed light on the underlying mechanisms affected by deposition temperature are proposed at the end of the article.

Funder

National Science and Technology Council

Publisher

AIP Publishing

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