Affiliation:
1. Interdisciplinary Center for Scientific Computing, Ruprecht-Karls University , Im Neuenheimer Feld 205, 69120 Heidelberg, Germany
Abstract
In this paper we present the Markovian Multiagent Monte-Carlo Second Order Self-Consistent Field Algorithm (M3-SOSCF). This algorithm provides a highly reliable methodology for converging SCF calculations in single-reference methods using a modified differential evolution approach. Additionally, M3 is embarrassingly parallel and modular in regards to Newton–Raphson subroutines. We show that M3 is able to surpass contemporary SOSCFs in reliability, which is illustrated by a benchmark employing poor initial guesses and a second benchmark with SCF calculations which face difficulties using standard SCF algorithms. Furthermore, we analyse inherent properties of M3 and show that in addition to its robustness and efficiency, it is more user-friendly than current SOSCFs.
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Cited by
1 articles.
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