Affiliation:
1. 1Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan
Abstract
The synthesis, crystal structure, and characterization of a silicon-silicon triply bonded species, disilyne with two bis[bis(trimethylsilyl)methyl]isopropylsilyl substituents, are described. The nature of the sp-hybridized silicon atoms is discussed from the viewpoint of spectroscopic results and theoretical calculations. The reactivity of the disilyne with alkali metals, tBuLi, and π-bonded compounds such as cis- and trans-2-butenes and phenylacetylene is also described.
Subject
General Chemical Engineering,General Chemistry
Reference48 articles.
1. Weidenbruch The Chemistry of Organic Silicon Compounds Chap;Rappoport,2001
Cited by
89 articles.
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