Affiliation:
1. 1Institut für Organische Chemie der Technischen Universität Berlin, Straße des 17. Juni 135, D-10623 Berlin, Germany
Abstract
Concepts for the activation of methane are derived from ion-molecule reactions of mass-selected, ground-state transition-metal cations M+. Elementary steps of industrially important processes are uncovered (e.g., oxygenation of methane or its coupling with carbon dioxide). In addition, the implications of the electronic structures of M(CH2)+ complexes for their reactions with nucleophiles are discussed, and the crucial role of contemporary quantum mechanical calculations in the elucidation of mechanistic details is emphasized.
Subject
General Chemical Engineering,General Chemistry
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