Studying the Mechanisms of Nitro Compounds Reduction (A-Review)-Reference-Cited by-同舟云学术

Studying the Mechanisms of Nitro Compounds Reduction (A-Review)

Published:2019-01-21 Issue:1 Volume:35 Page:22-38
ISSN:0970-020X
Container-title:Oriental Journal of Chemistry
language:
Short-container-title:Orient. J. Chem

Author:

Sassykova L. R.¹^ORCID,Aubakirov Y. A.²,Sendilvelan S.³,Tashmukhambetova Zh. Kh.¹,Zhakirova N. K.¹,Faizullaeva M. F.⁴,Batyrbayeva A. A.¹,Ryskaliyeva R. G.¹,Tyussyupova B. B.¹,Abildin T. S.¹

Affiliation:

1. Al-Farabi Kazakh National University, 71, al-Farabi ave., 050040, Almaty, Kazakhstan.

2. Al-Farabi Kazakh National University, 71, al-Farabi ave., 050040, Almaty, Kazakhstan.C

3. Department of Mechanical Engineering, Dr. M.G.R Educational and Research Institute, University, Chennai, 600 095, India.

4. Korkyt Ata Kyzylorda University, 29a Aiteke bi str., Kyzylorda, Kazakhstan.

Abstract

The article describes some variants of mechanisms of nitro compounds reduction, offered by authors in the scientific literature. The focus is on the description of the work of Kazakh and Russian chemists working in the field of catalysis. In most of the works, the classical scheme of the mechanism of the hydrogenation of Haber-Lukashevich nitrobenzene is confirmed and detailed by experimental methods. One of the interesting aspect of the article is description the mechanism of Ya.A. Dorfman which used the orbital theory of catalysis. The orbital approach of the Ya.A. Dorfman mechanism is constructed in the light of modern orbital representations and is valid for the hydrogenation of the nitro group on various catalysts. Among the discussed mechanisms are ideas of Haber, Debus, Jungers, V.P. Shmonina, Lukashevich, M. Geirovsky, Yu. B. Vasilyev, M.V. Klyuev, E.F. Weinstein, E. Gelder, Ya.A. Dorfman and others.

Publisher

Oriental Scientific Publishing Company

Subject

Drug Discovery,Environmental Chemistry,Biochemistry,General Chemistry

Reference71 articles.

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2. Aubakirov, Y.A.; Sassykova, L.R., Selective catalytic reduction of aromatic nitro compounds and hydrocarbons, Almaty, Qazaq university, 2018, 338.

3. Sokolsky, D.V.; Drouz, V.A., Reports of the Academy of Sciences of the USSR, 1950, 73(5), 949-950.

4. Shmonina, V.P .; Tarasova, D.V .; Alekseeva, G.K; Serazetdinova, V.A, Proceedings of the Institute of Chemical Sciences, Academy of Sciences of the Kazakh SSR, 1952, 8, 64-72.

5. Lukashevich, O.V., Journal of General Chemistry, 1937, 7, 2209-2213.

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