Author:
Zheng Mingtao,Zhang Haoran,Gong Xuebin,Xu Ruchun,Xiao Yong,Dong Hanwu,Liu Xiaotang,Liu Yingliang
Abstract
Abstract
A simple additive-free approach is developed to synthesize uniform manganese monoxide (MnO) one-dimensional nanorods, in which only manganese acetate and ethanol were used as reactants. The as-synthesized MnO nanorods were characterized in detail by X-ray diffraction, scanning and transmission electron microscopy (TEM) including high-resolution TEM and selected-area electron diffraction, Fourier transform infrared spectrum, and nitrogen adsorption isotherm measurements. The results indicate that the as-synthesized MnO nanorods present a mesoporous characteristic with large specific surface area (153 m2 g−1), indicating promising applications in catalysis, energy storage, and biomedical image. On the basis of experimental results, the formation mechanism of MnO one-dimensional nanorods in the absence of polymer additives was also discussed.
Publisher
Springer Science and Business Media LLC
Subject
Condensed Matter Physics,General Materials Science
Reference45 articles.
1. Wang X, Li YD: Selected-control hydrothermal synthesis of alpha- and beta-MnO2 single crystal. J Am Chem Soc 2002, 124: 2880–2881.
2. Li ZQ, Ding Y, Xiong YJ, Yang Q, Xie Y: One-step solution-based catalytic route to fabricate novel alpha-MnO2 hierarchical structures on a large scale. Chem Commun 2005, 7: 918–920.
3. Wang LZ, Sakai N, Ebina Y, Takada K, Sasaki T: Inorganic multilayer films of manganese oxide nanosheets and aluminum polyoxocations: fabrication, structure, and electrochemical behavior. Chem Mater 2005, 17: 1352–1357.
4. El-Deab MS, Ohsaka T: Manganese oxide nanoparticles electrodeposited on platinum are superior to platinum for oxygen reduction. Angew Chem Int Ed 2006, 45: 5963–5966.
5. Li WN, Yuan JK, Gomez-Mower S, Xu LP, Sithambaram S, Aindow M, Suib SL: Hydrothermal synthesis of structure- and shape-controlled manganese oxide octahedral molecular sieve nanomaterials. Adv Funct Mater 2006, 16: 1247–1253.
Cited by
91 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献