Effect of polyethylene cross-linking on properties of foams

Author:

Głuszewski Wojciech1,Stasiek Andrzej2,Raszkowska-Kaczor Aneta2,Kaczor Daniel3

Affiliation:

1. Institute of Nuclear Chemistry and Technology 16 Dorodna St., 03-195 Warsaw , Poland

2. Institute for Engineering of Polymer Materials and Dyes 55 M. Skłodowskiej-Curie St., 87-100 Toruń , Poland

3. Faculty of Chemistry Nicolaus Copernicus University 7 Gagarina St., 87-100 Toruń , Poland

Abstract

Abstract The process of cross-linking of polyethylene using gamma radiation (γ) and electron beam (EB) was tested from the point of view of density of foam. Particular attention was paid to the postradiation oxidation effect of the polymers. The study used two types of radiation sources of varying dose rates: gamma radiation (4 kGy/h) and EB (14 000 kGy/h). Radiolysis studies of the polymers used the radiation yield of hydrogen evolved (G H2 , approximately proportional to the number of radicals) and radiation yield of oxygen absorbed by the polymer (G O2 ). Oxidation of polymer due to radiation was also evaluated using diffuse reflectance spectroscopy.

Publisher

Walter de Gruyter GmbH

Subject

Waste Management and Disposal,Condensed Matter Physics,Safety, Risk, Reliability and Quality,Instrumentation,Nuclear Energy and Engineering,Nuclear and High Energy Physics

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