Solvent reduced wittig olefination reactions with halo containing conjugated phosphoranes-Reference-Cited by-同舟云学术

Solvent reduced wittig olefination reactions with halo containing conjugated phosphoranes

Published:2006-09-01 Issue:3 Volume:4 Page:403-427
ISSN:2391-5420
Container-title:Open Chemistry
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Author:

Thiemann Thies¹,Tanaka Yasuko¹,Ideta Keiko¹,Mataka Shuntaro¹

Affiliation:

1. 1Institute of Materials Chemistry and Engineering, Kyushu University, Kasuyga-shi, Fukuoka, 816-8580, Japan

Abstract

AbstractThe Wittig reaction of carbaldehydes with alkoxycarbonylhalomethylidenetriphenylphosphoranes can be performed with ease in solventless systems. The analogous reaction of carbaldehydes with acylhalomethylidenetriphenylphosphoranes requires a small amount of solvent, such as chloroform, in order for the reaction to proceed. The products of the reaction are versatile precursors for further transformations, such as the Suzuki-Miyaura cross-coupling reaction.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,General Chemistry

Link

http://link.springer.com/content/pdf/10.2478/s11532-006-0024-2.pdf

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