Formation and multinuclear magnetic resonance investigation of silylammonium tetracarbonylcobaltate contact ion pairs-Reference-Cited by-同舟云学术

Formation and multinuclear magnetic resonance investigation of silylammonium tetracarbonylcobaltate contact ion pairs

Published:2006-06-01 Issue:2 Volume:4 Page:299-316
ISSN:2391-5420
Container-title:Open Chemistry
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Author:

Sisak Attila¹,Szalontai Gábor.²

Affiliation:

1. 1Research Group for Petrochemistry, Hungarian Academy of Sciences, H-8200, Veszprém, Hungary

2. 2Department of Silicate and Materials Engineering, NMR laboratory, University of Veszprém, H-8200, Veszprém, Hungary

Abstract

AbstractSilylcobalt tetracarbonyls were reacted with various amines (B) in non-polar solvents to form silylammonium tetracarbonylcobaltate contact ion pairs formulated as [BSiR3+, −Co(CO)4]. The compounds were characterized by IR and multinuclear magnetic resonance spectroscopy both in solution and in solid state. Their properties are analogous to the known ion pairs [BH+, −Co(CO)4] and to amine adducts of halosilanes as well.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,General Chemistry

Link

http://link.springer.com/content/pdf/10.2478/s11532-006-0005-5.pdf

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