Influence of “Productive” Impurities (Cd, Na, O) on the Properties of the Cu2ZnSnS4 Absorber of Model Solar Cells
Author:
Sergeyev D.12, Zhanturina N.1, Aizharikov A.2, Popov A.I.3
Affiliation:
1. K. Zhubanov Aktobe Regional University , Aktobe , Kazakhstan 2. T. Begeldinov Aktobe Aviation Institute , Aktobe , Kazakhstan 3. Institute of Solid State Physics , University of Latvia , 8 Kengaraga Str ., Riga , Latvia
Abstract
Abstract
The study focuses on the optical properties of the CZTS multicomponent semiconductor absorber with 3 % “production” impurities of Cd, Na, O within the framework of the density functional theory using the generalized gradient approximation and the SCAPS program, as well as investigates their influence on the performance and efficiency of CZTS-solar cells. The results showed that the introduction of Cd, Na, O impurities would lead to a decrease in the intensity of the absorption bands at 2.06 eV and 2.55 eV. The density of states CZTS: (Cd, Na, O) was determined from first principles, and it was revealed that impurities of Cd and O atoms would lead to a decrease in the band gap (to 0.9 eV and 0.79 eV), and an increase in Na impurity absorption (1.2 eV). It was also found that a decrease in the band gap led to a decrease in the open circuit voltage, and it was also shown that “industrial” impurities led to a decrease in the efficiency of energy conversion of solar cells to 2.34 %.
Publisher
Walter de Gruyter GmbH
Subject
Psychiatry and Mental health,Neuropsychology and Physiological Psychology
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2 articles.
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