The Properties of Thermochemical Remanent Magnetization Acquired by Slow Laboratory Cooling of Titanomagnetite-Bearing Basalt Samples from Different Temperatures and the Results of the Thellier Method

Abstract

Abstract—The experiments have been carried out on the acquisition of thermochemical remanent magnetization (TCRM) in basalt samples containing titanomagnetite (TM) with the Curie temperature Тс ~200°C by their rapid heating to maximum temperatures Т* from 450 to 530°C followed by slow cooling in the laboratory magnetic field Blab. At different stages of the preliminary thermal treatment of the initial samples, a set of magnetomineralogical studies including electron microscopy, X-ray diffraction and thermomagnetic analyzes, and measurements of magnetic hysteresis parameters were performed. It is shown that as early as the very beginning of the cooling process, all samples demonstrate explosive growth of TCRM corresponding to the stage of rapid single-phase oxidation of the initial titanomagnetite fraction of basalt, and that TCRM is acquired by the increase of Тс and volume of single-phase oxidized parts of TM grains as well as by the growth of the volume of Ti-depleted (relative to the initial TM) cells of microstructure of the subsequent oxidative exsolution. The Arai–Nagata diagrams for the samples carrying TCRM have a form of a broken line consisting of two linear segments. The low-temperature interval T < Т* corresponds to a mixture of thermochemical and thermoremanent (TRM) magnetizations and gives a slightly overestimated Blab because of the effect of a low cooling rate during the acquisition of TCRM and TRM. The high-temperature interval corresponds to pure TCRM and the Blab strength determined from this interval is underestimated by 20–27%. It is recommended to reject samples whose Araii–Nagata diagram has two or more linear segments against the background single-component NRM.