Radiation shielding and spectroscopic features of replacement materials: Reusing of agricultural and industrial wastes

Abstract

Environmental pollution increases due to the large amounts of waste production and raw material consumption depending on the increasing population. Agricultural and industrial wastes which are some of the sources of the pollution need to be reuse to reduce the negative impact on the environment and also contribute positive effect to the economy. In this context, industrial wastes such as clay types (red and green) and agricultural wastes such as egg shell, walnut shell and banana shell were used to prepare materials which can be used as replacement materials for construction industry. Radiation attenuation parameters (mass attenuation coefficients, effective atomic number, linear attenuation coefficients, mean free path, half-value layer, exposure and energy absorption build up factors, fast neutron removal cross-section) were acquired by Phy-X/PSD code. Spectroscopic techniques (XRD, EPR, SEM-EDS) were performed for the structural analysis. The existence of calcite main phase peaks (≈29.7) as well as SiO2 (≈20° and 26°) and cellulose phases (≈16° and 34.7°) were observed by XRD. Mn+2 sextet lines with five weak doublets attributed to the forbidden transition lines of Mn+2 and a singlet with a g value of ≈2.00 and linewidth of ≈10 G were recorded by EPR. Among the samples, it was found that K1 (Red clay (20%)-eggshell waste (60%)-Bayburt stone waste (20%)), K3 (Red clay (60%)-eggshell waste (20%)-Bayburt stone waste (20%)), C3 (Red clay (60%)-eggshell waste (20%)-walnut shell waste (20%)) and Z3 (Green clay (60%)-egg shell waste (20%)-Bayburt stone waste (20%)) have the highest shielding potentials. All samples examined with good protection performances can be used as substitute materials instead of cement or aggregate for the aim of reusing the wastes and supporting the environmental and economic benefits.