The structure of solid CF3I-Reference-Cited by-同舟云学术

The structure of solid CF3I

Published:1993-01-01 Issue:1 Volume:206 Page:87-95
ISSN:2194-4946
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Clarke Simon J.,Cockcroft Jeremy K.,Fitch Andrew N.

Abstract

Abstract Powder neutron diffraction studies of solid CF3I indicate that there are two solid-state phases with a transition temperature of 115 K. The structure of the higher-temperature phase I, which melts at approximately 143 K, has been determined from high-resolution powder diffraction data. The structure is orthorhombic, space group Cmca, Z = 8, with a = 7.5354(7) Å, b = 5.8491(6) Å, c = 19.323(1) Å at 130 K. The structure consists of bilayers of iodine atoms interspaced with bilayers of CF3 groups.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1524/zkri.1993.206.Part-1.87/pdf

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