Empirical Models of the Pair-Polarizability Trace and Anisotropy from Polarized and Depolarized Interaction-Induced Light Scattering Spectra for Gaseous Krypton

Abstract

Abstract A method based on classical physics, utilizing the first few even moments of the polarized and depolarized interaction-induced light scattering spectra at room temperature to derive an empirical model for the pair-polarizability trace and anisotropy of interacting atoms, with adjustable free parameters, is described and applied to the spectra of krypton. Good agreement with ab initio and analytical results in the literature is obtained and profiles calculated with our empirical models are in excellent agreement with experiments. Theoretical calculations using these models are compared with the experimental values of the second dielectric constant and second virial Kerr coefficient for this gas. The results show excellent agreement with the experiments.