The Heterogeneous Kinetics of the Reactions ClONO2 + HX/ice (X = Br, I), BrONO2 + HI/ice and the Reactivity of the Interhalogens BrCl, ICl and IBr with HX/ice (X = Cl, Br, I) in the Temperature Range 180 to 205 K

Abstract

The kinetics and mechanism of the title heterogeneous halogen exchange reactions of potential atmospheric importance have been studied under molecular flow conditions in a FEP Teflon-coated Knudsen flow reactor on HX (X = Cl, Br, I) - doped ice condensed from the vapor phase under conditions of several formal monolayers of HX coverage at approximately 200 K. In addition, the halogen exchange reactions involving the expected primary reaction products BrCl, ICl and IBr of the above mixed anhydrides with HX-doped ice have been studied at 200 K as well. The uptake coefficient γ for the heterogeneous reaction ClONO