Affiliation:
1. Hefei National Laboratory for Physical Science at the Microscale and Department of Chemistry, University of Science and Technology of China
2. Center for Excellence in Molecular Synthesis of CAS
Abstract
AbstractAsymmetric dihydroxylation of alkenes is one of the cornerstone reactions in organic synthesis, providing a direct entry to optically active vicinal diols, which are not only a subunit in natural products but also versatile building blocks. In recent years, considerable progress in catalytic asymmetric osmium-free dihydroxylation has been achieved. This short review presents a concise summary of the reported methods of catalytic asymmetric osmium-free dihydroxylation.1 Introduction2 Iron-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes3 Manganese-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes4 Palladium/Gold Bimetallic Nanocluster-Catalyzed Asymmetric syn-Dihydroxylation of Alkenes5 Enzyme-Catalyzed Asymmetric anti-Dihydroxylation of Alkenes6 Amine-Catalyzed Asymmetric Formal anti-Dihydroxylation of Enals7 Diselenide-Catalyzed anti-Dihydroxylation of Alkenes8 Molybdenum-Catalyzed Asymmetric anti-Dihydroxylation of Allylic Alcohols9 Phase-Transfer-Catalyzed Asymmetric Dihydroxylation of α-Aryl Acrylates10 Conclusion
Funder
National Natural Science Foundation of China
Fundamental Research Funds for the Central Universities
University of Science and Technology of China
Subject
Organic Chemistry,Catalysis
Cited by
9 articles.
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