Regioselective Diboron-Mediated Semireduction of Terminal Allenes-Reference-Cited by-同舟云学术

Regioselective Diboron-Mediated Semireduction of Terminal Allenes

Published:2019-10-10 Issue:24 Volume:51 Page:4619-4624
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Gates Ashley M.,Santos Webster L.¹^ORCID

Affiliation:

1. Department of Chemistry, Virginia Tech

Abstract

A method for the regioselective reduction of the terminal double bond of 1,1-disubstituted allenes has been developed. In the presence of a palladium catalyst, tetrahydroxydiboron and stoichiometric water, allene semireduction proceeds in high yield to afford Z-alkenes selectively.

Funder

National Science Foundation

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0039-1690207.pdf

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1. Pd-Catalyzed Transfer Hydrogenation of Alkenes Using Tetrahydroxydiboron as the Sole Hydrogen Donor;SynOpen;2024-07-16

2. Transfer Hydrogenolysis of O‐ and N‐Benzyl Groups in Water with Tetrahydroxydiboron by Using an Amphiphilic Polymer‐Supported Nano‐Palladium Catalyst;European Journal of Organic Chemistry;2024-05-17

3. Interplay of Ligand-Controlled Reaction Pathways: DFT Analysis of Mechanisms and Selectivities in Pd-Catalyzed Semireduction of Allenamides;Molecular Catalysis;2024-05

4. Transfer hydrogenation of aldehydes and ketones with tetrahydroxydiboran in water by an amphiphilic resin-supported nano-palladium catalyst;Chemistry Letters;2024-05

5. Tetrahydroxydiboron (Bis‐boric Acid): a Versatile Reagent for Borylation, Hydrogenation, Catalysis, Radical Reactions and H₂ Generation;European Journal of Inorganic Chemistry;2023-03-09