N-Heterocyclic Carbene Catalyzed Stereoselective Synthesis of 2-Nitro-thiogalactosides
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Published:2019-06-26
Issue:18
Volume:51
Page:3451-3461
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ISSN:0039-7881
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Container-title:Synthesis
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language:en
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Short-container-title:Synthesis
Author:
Hu Yu-Long,Gou Bo-Bo,Wang Jiao,Zhao Ming,Liu Jia-Lin,Chen Jie,Zhou Ling
Abstract
A highly selective NHC-catalyzed Michael addition of alkanethiols or thiophenol to 2-nitro-d-galactal compounds for the synthesis of 2-nitro-thiogalactoside derivatives has been developed for the first time. A wide variety of 1,2-cis-2-nitro-thiogalactosides can be prepared in good to excellent yields and high to excellent α-selectivities.
Funder
Shaanxi Provincial Science and Technology Department
National Natural Science Foundation of China
China Postdoctoral Science Foundation
Natural Science Foundation of Shaanxi Province
Publisher
Georg Thieme Verlag KG
Subject
Organic Chemistry,Catalysis
Cited by
2 articles.
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