Affiliation:
1. Department of Chemistry, School of Chemical Sciences and Pharmacy, Central University of Rajasthan
2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Abstract
AbstractProline-histidine dipeptide laid the foundation for the construction of three new ion-tagged organocatalysts, utilising the imidazole moiety of histidine for generating the quaternary species. A brief comparative investigation of the catalysts in the enamine-mediated direct asymmetric aldol reaction brought out their contrasting features, particularly under aqueous conditions. The best among them was also utilised in preparing some derivatives and effecting a desymmetrisation.
Funder
Department of Science and Technology, Ministry of Science and Technology, India
Russian Foundation for Basic Research
Council of Scientific and Industrial Research, India
Department of Science and Technology-Fund for Improvement of S&T Infrastructure in Universities and Higher Educational Institutions
University Grants Commission
Subject
Organic Chemistry,Catalysis
Cited by
2 articles.
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