Affiliation:
1. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University
2. Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University
3. Hefei National Laboratory for Physical Sciences at the Microscale, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China
Abstract
Alkenes are ubiquitous in Nature and their functionalization continues to attract attention from the scientific community. On the other hand, activation of alkenyl sp2 C–H bonds is challenging due to their chemical properties. In this short account, we elucidate, discuss and describe the utilization of transition-metal catalysts in alkene activation and provide useful strategies to synthesize organic building blocks in an efficient and sustainable manner.1 Introduction2 Breakthrough3 Controlling E/Z, Z/E Selectivity3.1 Esters and Amides as Directing Groups3.2 The Chelation versus Non-Chelation Concept4 Other Alkene Derivatives5 Intramolecular C–H Activation6 Conclusion and Future Projects
Funder
Nanyang Technological University, Singapore Ministry of Education Academic Research Fund
Singapore National Research Foundation
State Key Program of the National Natural Science Foundation of China
National Natural Science Foundation of China
State Key Laboratory of Elemento-organic Chemistry, Nankai University
Collaborative Innovation Center of Chemistry for Energy Materials
Subject
Organic Chemistry,Catalysis
Cited by
55 articles.
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