Indium-, Magnesium-, and Zinc-Mediated Debenzylation of Protected 1H-Tetrazoles: A Comparative Study-Reference-Cited by-同舟云学术

Indium-, Magnesium-, and Zinc-Mediated Debenzylation of Protected 1H-Tetrazoles: A Comparative Study

Published:2018-06-25 Issue:17 Volume:50 Page:3430-3435
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Behloul Cherif¹,Foubelo Francisco²³⁴,Benlahrech Meriem¹,Nájera Carmen²⁴,Yus Miguel²⁴

Affiliation:

1. Laboratoire des Produits Naturels d'Origine Végétale et de Synthèse Organique, Université Frères Mentouri Constantine1

2. Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Alicante

3. Instituto de Síntesis Orgánica (ISO), Universidad de Alicante

4. Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad de Alicante

Abstract

5-Substituted 1-benzyltetrazoles are easily debenzylated to give the corresponding deprotected tetrazoles using dissolved metals under protic conditions: Mg/MeOH, In/MeOH, or Zn/MeCO2H are the procedures of choice for this transformation.

Funder

Spanish Ministerio de Ciencia e Innovación

Ministerio de Economía y Competitividad

Generalitat Valenciana

Spanish Ministerio de Asuntos Exteriores y de Cooperación

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0037-1610170.pdf

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