Visible-Light-Promoted Difunctionalization of Olefins Leading to α-Thiocyanato Ketones-Reference-Cited by-同舟云学术

Visible-Light-Promoted Difunctionalization of Olefins Leading to α-Thiocyanato Ketones

Published:2018-04-23 Issue:10 Volume:29 Page:1340-1345
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Nan Guangming¹,Yue Huilan²

Affiliation:

1. University and College Key Lab of Natural Product Chemistry and Application in Xinjiang, School of Chemistry and Environmental Science, Yili Normal University

2. Key Laboratory of Tibetan Medicine Research, Northwest Institute of Plateau Biology, Chinese Academy of Sciences and Qinghai Provincial Key Laboratory of Tibetan Medicine Research

Abstract

A simple and convenient visible-light-induced difunctionalization of alkenes with ammonium thiocyanate and dioxygen has been developed at room temperature. A series of α-thiocyanato ketones could be easily and efficiently obtained in moderate to good yields through the formation of C–S and C=O bonds simply by using nontoxic and inexpensive Na2-Eosin Y as a photocatalyst.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0037-1609443.pdf

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