Biology-Oriented Synthesis of Decahydro-4,8-epoxyazulene Scaffolds-Reference-Cited by-同舟云学术

Biology-Oriented Synthesis of Decahydro-4,8-epoxyazulene Scaffolds

Published:2017-08-23 Issue:20 Volume:28 Page:2918-2922
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Jia Zhi-Jun¹²,Merten Christian³,Knauer Lena⁴,Murarka Sandip⁵,Strohmann Carsten⁴,Waldmann Herbert¹²

Affiliation:

1. Department of Chemical Biology, Max Planck Institute of Molecular Physiology

2. Chemical Biology, Faculty of Chemistry and Chemical Biology, Technical University Dortmund

3. Ruhr-Universität Bochum, Lehrstuhl für Organische Chemie II

4. Inorganic Chemistry, Faculty of Chemistry and Chemical Biology,Technical University Dortmund

5. Department of Chemistry, IIT Jodhpur

Abstract

Guided by the principle of biology-oriented synthesis, a collection of compounds with decahydro-4,8-epoxyazulene scaffold occurring in bioactive natural products was synthesized by the rhodium(II)-catalyzed 1,3-dipolar cycloaddition reaction of pentafulvenes and carbonyl ylides. The products can be obtained in moderate to high yields, with moderate enantioselectivity and excellent diastereoselectivity and regioselectivity.

Funder

H2020 European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1588558.pdf

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