Affiliation:
1. Department of Chemistry, Shanghai Jiao Tong University
Abstract
Imides are prepared conveniently by visible-light-driven oxidations of various N-alkylamides under mild conditions. The majority of the reactions proceed efficiently by using Oxone as the oxidant in the presence of a catalytic amount of KBr in H2O/CH2Cl2 under irradiation by an 8 W white LED at room temperature. Experimental studies suggest that an imine, obtained from the substrate amide via a radical process, is the key intermediate.
Funder
National Natural Science Foundation of China
Subject
Organic Chemistry,Catalysis
Cited by
16 articles.
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