Recent Progress in the Cross-Coupling Reaction Using Triorgano­silyl-Type Reagents

Author:

Minami Yasunori1,Hiyama Tamejiro1ORCID,Komiyama Takeshi2

Affiliation:

1. Research and Development Initiative, Chuo University

2. Department of Applied Chemistry, Chuo University

Abstract

The silicon-based cross-coupling reaction has attracted much attention over recent decades because there are many advantages in using organosilicon compounds. However, the use of reagents with a triorganosilyl group as a key function remains to be established. This account summarizes our recent progress in cross-coupling chemistry with such silyl reagents.1 Introduction2 Preparation of HOMSi Reagents from Aryl Bromides and Disilanes3 HOMSi Reagents from Heteroaromatics and Hydrosilanes4 Cross-Coupling Polymerization with HOMSi Reagents5 Cross-Coupling with Aryl(triethyl)silanes6 Amination of Aryl Halides with N-TMS-Amines7 Conclusion and Perspective

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

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