Electrochemical reduction of nitrate to hydroxylamine on gold electrode

Author:

Xie Yangshan1,De Ras Michiel2ORCID,Zhao Jiwu34,Liu Tianxi5,Lai Feili5ORCID,Hofkens Johan26ORCID,Roeffaers Maarten B. J.1ORCID

Affiliation:

1. Centre for Membrane Separations, Adsorption, Catalysis, and Spectroscopy for Sustainable Solutions, Department of Microbial and Molecular Systems, KU Leuven Celestijnenlaan 200F, 3001 Leuven, Belgium

2. Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven, 3001, Belgium

3. State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China

4. Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955–6900, Saudi Arabia

5. The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, International Joint Research Laboratory for Nano Energy Composites, Jiangnan University, Wuxi, China

6. Max Plank Institute for Polymer Research, Mainz, D-55128, Germany

Abstract

A highly effective electrocatalyst of Au has been applied for the selective NO3 electroreduction to NH2OH through meticulous experimentation involving electrolyte composition, nitrate concentration, pH and applied potential.

Funder

National Natural Science Foundation of China

KU Leuven

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

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