Complexation of NpO2+ with (2-hydroxyethyl)ethylenediaminetriacetic acid (HEDTA) in aqueous solutions: thermodynamic studies and structural analysis

Author:

Li Xingliang12345ORCID,Zhang Zhicheng1234ORCID,Martin Leigh R.6784ORCID,Luo Shunzhong591011,Rao Linfeng1234

Affiliation:

1. Chemical Sciences Division

2. Lawrence Berkeley National Laboratory

3. Berkeley

4. USA

5. Institute of Nuclear Physics and Chemistry

6. Aqueous Separations and Radiochemistry Department

7. Idaho National Laboratory

8. Idaho Falls

9. China Academy of Engineering Physics

10. Mianyang

11. China

Abstract

The complexation of Np(v) with HEDTA in aqueous solutions was investigated by spectrophotometry, microcalorimetry and EXAFS. Thermodynamic parameters were determined and coordination modes also discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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