Co(i) complexes with a tetradentate phenanthroline-based PNNP ligand as a potent new metal–ligand cooperation platform-Reference-Cited by-同舟云学术

Co(i) complexes with a tetradentate phenanthroline-based PNNP ligand as a potent new metal–ligand cooperation platform

Published:2020 Issue:41 Volume:49 Page:14592-14597
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jheng Nai-Yuan¹²³⁴⁵^ORCID,Ishizaka Yusuke¹²³⁴⁵^ORCID,Naganawa Yuki⁵⁶³⁴^ORCID,Sekiguchi Akira⁵⁶³⁴^ORCID,Nakajima Yumiko¹²³⁴⁵^ORCID

Affiliation:

1. Graduate School of Pure and Applied Sciences

2. University of Tsukuba

3. Tsukuba

4. Japan

5. Interdisciplinary Research Center for Catalytic Chemistry (IRC3)

6. National Institute of Advanced Industrial Science and Technology (AIST)

Abstract

A cobalt(i) alkyl complex bearing a tetradentate phenanthroline-based PNNP ligand undergoes dearomatization of the ligand backbone skeleton upon heating and furthermore achieves H–H bond cleavage.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02549F

Reference57 articles.

1. Dicobalt Octacarbonyl as a Catalyst for Hydrosilation of Olefins

2. Photochemical Reaction of [(CO)4Co(SiEt3)] with Ethylene: Implications for Cobaltcarbonyl-Catalyzed Hydrosilation of Alkenes

3. Activation of sp3 C−H Bonds with Cobalt(I): Catalytic Synthesis of Enamines

4. Development of more labile low electron count Co(i) sources: mild, catalytic functionalization of activated alkanes using a [(Cp*Co)2-μ-(η4:η4-arene)] complex

5. Molecular mechanisms of cobalt-catalyzed hydrogen evolution

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