A comparison of hydrogen release kinetics from 5- and 6-membered 1,2-BN-cycloalkanes-Reference-Cited by-同舟云学术

A comparison of hydrogen release kinetics from 5- and 6-membered 1,2-BN-cycloalkanes

Published:2021 Issue:54 Volume:11 Page:34132-34136
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Giustra Zachary X.¹,Chen Gang¹,Vasiliu Monica²,Karkamkar Abhijeet³,Autrey Tom³,Dixon David A.²^ORCID,Liu Shih-Yuan¹^ORCID

Affiliation:

1. Department of Chemistry, Boston College, Chestnut Hill, Massachusetts 02467-3860, USA

2. Department of Chemistry, The University of Alabama, Tuscaloosa, Alabama 35487-0036, USA

3. Pacific Northwest National Laboratories, Richland, Washington 99353, USA

Abstract

The reaction order and Arrhenius activation parameters for spontaneous hydrogen release from cyclic amine boranes, i.e., BN-cycloalkanes, were determined for 1,2-BN-cyclohexane (1) and 3-methyl-1,2-BN-cyclopentane (2) in tetraglyme.

Funder

U.S. Department of Energy

University of Alabama

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA07477F

Reference44 articles.

1. Will We Soon Be Fueling our Automobiles with Ammonia–Borane?

2. B–N compounds for chemical hydrogenstorage

3. Ammonia-Borane and Related Compounds as Dihydrogen Sources

4. Solid-state hydrogen rich boron–nitrogen compounds for energy storage

5. Nanoscaffold Mediates Hydrogen Release and the Reactivity of Ammonia Borane

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