Iridium-catalyzed enantioselective intramolecular hydroarylation of allylic aryl ethers devoid of a directing group on the aryl group-Reference-Cited by-同舟云学术

Iridium-catalyzed enantioselective intramolecular hydroarylation of allylic aryl ethers devoid of a directing group on the aryl group

Published:2021 Issue:99 Volume:57 Page:13542-13545
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ohmura Toshimichi¹^ORCID,Kusaka Satoshi¹,Suginome Michinori¹^ORCID

Affiliation:

1. Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

The Ir/(S)-DTBM-SEGPHOS catalyst promotes intramolecular hydroarylation of allylic aryl ethers without assistance from a directing group on the aryl groups.

Funder

Asahi Glass Foundation

Tonen General Sekiyu Research/Development Encouragement and Scholarship Foundation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC05684K

Reference37 articles.

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5. Rhodium(III)-Catalyzed Intramolecular Hydroarylation, Amidoarylation, and Heck-type Reaction: Three Distinct Pathways Determined by an Amide Directing Group

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