Superatom–atom super-bonding in metallic clusters: a new look to the mystery of an Au20 pyramid-Reference-Cited by-同舟云学术

Superatom–atom super-bonding in metallic clusters: a new look to the mystery of an Au20 pyramid

Published:2014 Issue:21 Volume:6 Page:12440-12444
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Cheng Longjiu¹²³,Zhang Xiuzhen¹²³,Jin Baokang¹²³,Yang Jinlong⁴⁵³

Affiliation:

1. Department of Chemistry

2. Anhui University

3. Hefei, People's Republic of China

4. Hefei National Laboratory for Physics Sciences at the Microscale

5. University of Science & Technology of China

Abstract

Superatom–atom bonding in Au₂₀ : Au₂₀ can be viewed as a superatomic molecule, of which the superatomic 16c–16e core (T) is in D³S hybridization bonded with four vertical Au atoms for molecule-like (TAu₄) electronic shell-closure.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2014/NR/C4NR03550J

Reference61 articles.

1. Bonding in Cu, Ag, and Au Clusters: Relativistic Effects, Trends, and Surprises

2. Investigating the structural evolution of thiolate protected gold clusters from first-principles

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4. The gold–sulfur interface at the nanoscale

5. Quantum Sized Gold Nanoclusters with Atomic Precision

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