Chelation-assisted α and β C–H functionalization of aryl alkenes with alkynes and alkenes-Reference-Cited by-同舟云学术

Chelation-assisted α and β C–H functionalization of aryl alkenes with alkynes and alkenes

Published:2024 Issue:17 Volume:11 Page:4862-4868
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Cheng¹,Lin Yu¹,Zhu Yuhang¹,Peng Chengxing¹,Lv Binbin¹,Zhao Li¹^ORCID,Zhong Guofu¹²^ORCID,Wei Jinfeng³,Zhang Jian¹⁴^ORCID

Affiliation:

1. College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou, 311121, Zhejiang, China

2. Department of chemistry, Eastern Institute of Technology, Ningbo 315200, Zhejiang, China

3. Yanjia Oil Production Management Area of Dongxin Oil Production Plant in Shengli Oilfield, Dongying, 257000, Shandong, China

4. Department of Stomatology, The Affiliated Hospital of Hangzhou Normal University, Hangzhou Normal University, Hangzhou, 310015, Zhejiang, China

Abstract

α C–H alkenylation of aryl alkenes by six-membered exo-palladacycles was demonstrated to afford aryl dienes, which underwent β C–H alkenylation through seven-membered endo-palladacycles to produce aryl trienes with excellent E/Z ratio selectivity.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00325J

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