A carbene-stabilized diphosphorus: a triple-bonded diphosphorus (PP) and a bis(phosphinidene) (P–P) transfer agent

Author:

Yoon Joseph S.1,Abdellaoui Mehdi1ORCID,Gembicky Milan1ORCID,Bertrand Guy1ORCID

Affiliation:

1. UCSD-CNRS Joint Research Laboratory (IRL 3555), Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, CA 92093-0358, USA

Abstract

The bis-monosubstituted aminocarbene-P2 adduct is a generator of P2, under the classical triple-bonded form (PP), but it also acts as a bis(phosphinidene) (P–P) synthetic equivalent.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Reference48 articles.

1. M.Regitz and O. J.Scherer , Multiple Bonds and Low Coordination in Phosphorus Chemistry , Thieme , Stuttgart, Germany , 1990

2. K. B.Dillon , F.Mathey and J. F.Nixon , Phosphorus: The Carbon Copy , Wiley , Chichester, UK , 1998

3. Small Neutral Pn Molecules

4. Raman spectroscopic studies on matrix-isolated phosphorus molecules P4 and P2

5. Cp2Mo2(CO)4P2 as Complex Ligand

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