Cu-Catalysed sustainable synthesis of formamide with glycerol derivatives as a carbonyl source <i>via</i> a radical-relay mechanism-Reference-Cited by-同舟云学术

Cu-Catalysed sustainable synthesis of formamide with glycerol derivatives as a carbonyl source via a radical-relay mechanism

Published:2023 Issue:4 Volume:25 Page:1464-1472
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Dai Xingchao¹^ORCID,Wang Xinzhi²^ORCID,Kreyenschulte Carsten¹^ORCID,Yuan Hangkong²,Brückner Angelika¹^ORCID,Shi Feng²^ORCID,Rabeah Jabor¹^ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, 18059 Rostock, Germany

2. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, No. 18, Tianshui Middle Road, Lanzhou, 730000, China

Abstract

N-Formylation of amines to formamides was achieved at a low temperature by total utilization of the carbon atoms of glycerol derivatives as the C1 feedstock over CuZr/5A via a ˙OH–˙OOH radical mechanism.

Funder

National Natural Science Foundation of China

West Light Foundation of the Chinese Academy of Sciences

Science and Technology Program of Gansu Province

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D2GC03993A

Reference74 articles.