Dynamic nature of excited states of donor–acceptor TADF materials for OLEDs: how theory can reveal structure–property relationships

Author:

Olivier Yoann1234ORCID,Moral Mónica567,Muccioli Luca89101112ORCID,Sancho-García Juan-Carlos1314157

Affiliation:

1. Laboratory for Chemistry of Novel Materials

2. University of Mons

3. 7000 Mons

4. Belgium

5. Renewable Energy Research Institute University of Castilla-La Mancha

6. 02071 Albacete

7. Spain

8. Institut des Sciences Moléculaires

9. UMR 5255

10. University of Bordeaux

11. 33405 Talence

12. France

13. Departamento de Química Física

14. University of Alicante

15. 03080 Alicante

Abstract

In a theoretical study, we characterized the nature of the key excited states involved in the TADF process of donor–acceptor compounds and showed that light emission is enhanced by dynamic fluctuations of the donor–acceptor torsion resulting from flat torsional potentials.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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